Stanford University

Electronics are showing up everywhere: on our laps, in pockets and purses and, increasingly, snuggled up against our skin or sewed into our clothing.
But the adoption of wearable electronics has so far been limited by their need to derive power from bulky, rigid batteries that reduce comfort and may present safety hazards due to chemical leakage or combustion.
Now Stanford researchers have developed a soft and stretchable battery that relies on a special type of plastic to store power more safely than the flammable formulations used in conventional batteries today.
"Until now we haven't had a power source that could stretch and bend the way our bodies do, so that we can design electronics that people can comfortably wear," said chemical engineer Zhenan Bao, who teamed up with materials scientist Yi Cui to develop the device they describe in the Nov. 26 edition of Nature Communications.
The use of plastics, or polymers, in batteries is not new. For some time, lithium ion batteries have used polymers as electrolytes -- the energy source that transports negative ions to the battery's positive pole. Until now, however, those polymer electrolytes have been flowable gels that could, in some cases, leak or burst into flame.
To avoid such risks, the Stanford researchers developed a polymer that is solid and stretchable rather than gooey and potentially leaky, and yet still carries an electric charge between the battery's poles. In lab tests the experimental battery maintained a constant power output even when squeezed, folded and stretched to nearly twice its original length.
The prototype is thumbnail-sized and stores roughly half as much energy, ounce for ounce, as a comparably sized conventional battery. Graduate student David Mackanic said the team is working to increase the stretchable battery's energy density, build larger versions of the device and run future experiments to demonstrate its performance outside the lab. One potential application for such a device would be to power stretchable sensors designed to stick to the skin to monitor heart rate and other vital signs as part of the BodyNet wearable technology being developed in Bao's lab.
Decoupling of mechanical properties and ionic conductivity in supramolecular lithium ion conductors
David G. Mackanic, Xuzhou Yan, Qiuhong Zhang, Naoji Matsuhisa, Zhiao Yu, Yuanwen Jiang, Tuheen Manika, Jeffrey Lopez, Hongping Yan, Kai Liu, Xiaodong Chen, Yi Cui & Zhenan Bao
Nature Communications volume 10, Article number: 5384 (2019)
DOI: 10.1038/s41467-019-13362-4
Contact information:
Zhenan Bao
Stanford Professor in Chemical Engineering
zbao@stanford.edu
Phone: (650) 723 9548/2419
Yi Cui
Stanford Professor in Materials Science and Engineering
yicui@stanford.edu
Phone: (650) 723 4613/0698

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