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High energy Li-Ion battery is safer for electric vehicles


Illustration of a new lithium-ion battery that is both safe and high-performing, developed by researchers at Penn State. @ Jennifer McCann/Penn State

Electric vehicle batteries typically require a tradeoff between safety and energy density. If the battery has high energy and power density, which is required for uphill driving or merging on the freeway, then there is a chance the battery can catch fire or explode in the wrong conditions. But materials that have low energy/power density, and therefore high safety, tend to have poor performance. There is no material that satisfies both. For that reason, battery engineers opt for performance over safety.


"In this work we decided we were going to take a totally different approach," said Chao-Yang Wang, professor of mechanical, chemical and materials science and engineering, and William E. Diefenderfer Chair in Mechanical Engineering, Penn State. "We divided our strategy into two steps. First we wanted to build a highly stable battery with highly stable materials."


Their second step was to introduce instant heating. About four years ago, Wang developed a self-heating battery to overcome the problem of poor performance in cold climates. The battery uses an electric current to heat up in seconds compared to the hours an external heater required. By heating the battery from room temperature to around 140 degrees Fahrenheit -- 60 degrees Celsius -- the battery gets an instant boost in reactivity because the law of kinetics is that reactivity increases exponentially with temperature.


"With these two steps I can get high safety when the battery is not being used and high power when it is," he said.


The self-heating battery, called the All Climate battery, has been adopted by several car companies, including BMW, and was chosen to power a fleet of 10,000 vehicles that will be used to ferry people between venues at the next Winter Olympics in Beijing.


The BEST Center tests the safety of the battery using nail penetration equipment. They drive the nail into the cell causing short circuiting. They then monitor the cell for temperature and voltage. The difference in temperature for the passivated cell was 212 degrees F -- 100 degrees C --compared to a standard battery cell which was 1,832 degrees F -- 1000 degrees C, an enormous improvement.


Because their batteries are built using stable materials, they have a long cycle life. Even at 140 degrees F, their cycle number is over 4000, which translates to over a million miles.


The team's next project will be to develop a solid-state battery, which will likely require heating as well.


The current work appears in the journal Science Advances and is titled "A new approach to both safety and high performance of lithium-ion batteries." Wang's coauthors are research assistant professors Shanhai Ge, Yongjun Leng and Xiao-Guang Yang, and doctoral students Teng Liu, Ryan Longchamps, Yue Gao and Daiwei Wang. Donghai Wang, professor of mechanical and of chemical engineering, Penn State, also participated in this work.


A new approach to both high safety and high performance of lithium-ion batteries

Shanhai Ge, Yongjun Leng, Teng Liu, Ryan S. Longchamps, Xiao-Guang Yang, Yue Gao, Daiwei Wang, Donghai Wang and Chao-Yang Wang

Science Advances 28 Feb 2020: Vol. 6, no. 9, eaay7633

DOI: 10.1126/sciadv.aay7633


Contact information:

Chao-Yang Wang

Penn State Professor of mechanical, chemical and materials science and engineering, and William E. Diefenderfer Chair in Mechanical Engineering

cxw31@psu.edu

Phone: (814) 863-4762

Battery and Energy Storage Technology (BEST) @ Penn State


Pennsylvania State University (Penn State)

 

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