A breakthrough in decoding the growth process of Hexagonal Boron Nitride (hBN), a 2D material, and its nanostructures on metal substrates could pave the way for more efficient electronics, cleaner energy solutions and greener chemical manufacturing, according to new research from the University of Surrey.
Only one atom thick, hBN – often nicknamed "white graphene" – is an ultra-thin, super-resilient material that blocks electrical currents, withstands extreme temperatures and resists chemical damage. Its unique versatility makes it an invaluable component in advanced electronics, where it can protect delicate microchips and enable the development of faster, more efficient transistors.
Going a step further, researchers have also demonstrated the formation of nanoporous hBN, a novel material with structured voids that allows for selective absorption, advanced catalysis and enhanced functionality, vastly expanding its potential environmental applications. This includes sensing and filtering pollutants – as well as enhancing advanced energy systems, including hydrogen storage and electrochemical catalysts for fuel cells.
Working in collaboration with Austria’s Graz University of Technology (TU Graz), the team - led by Dr Marco Sacchi, with the theoretical work performed by Dr Anthony Payne and Dr Neubi Xavier - combined density functional theory and microkinetic modelling to map the growth process of hBN from borazine precursors, examining key molecular processes such as diffusion, decomposition, adsorption and desorption, polymerisation, and dehydrogenation. This approach enabled them to develop an atomic scale model that allows for the material to be grown at any temperature.
The insights from the theoretical simulations align closely with experimental observations by the Graz research group, setting the stage for controlled, high-quality production of hBN with specific designs and functionality.
The study has been published in Small, with the research supported by the UK’s HPC Materials Chemistry Consortium and the Austrian Science Fund.
Reference
Unravelling the Epitaxial Growth Mechanism of Hexagonal and Nanoporous Boron Nitride: A First-Principles Microkinetic Model
Anthony J. R. Payne, Neubi F. Xavier Jr, Anton Tamtögl, Marco Sacchi
https://onlinelibrary.wiley.com/doi/10.1002/smll.202405404
University of Surrey
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