NW
← Newsroom
Material ScienceJune 5, 2019 · 1 min read

Materials—engineering heat transport

In a perfect thermoelectric crystal, vibrational waves decompose and localize. A diagram of simulated phonon energy versus momentum reveals exactly where heat transport stops because of vibrations interfering nonlinearly—the flat band between the curved top and V-shaped bottom bands. @ Michael Manley/Oak Ridge National Laboratory, U.S. Dept. of Energy

Scientists have discovered a way to alter heat transport in thermoelectric materials, a finding that may ultimately improve energy efficiency as the materials convert heat flow into electricity.

Caltech theorists simulating the thermoelectric material lead selenide saw something surprising—a thermal wave that did not propagate. They determined the trick to potentially increasing energy efficiency in this material was to stop heat-carrying vibrational waves without thwarting electricity-bearing electrons. To verify the discovery, they called on experimentalists to probe a real crystal.

“Vibrational waves stop propagating in a perfect crystal because of nonlinear interactions between phonons,” said Michael Manley of Oak Ridge National Laboratory.

The experiment used neutron scattering at ORNL’s Spallation Neutron Source and the National Institute of Standards and Technology’s Center for Neutron Research and X-ray scattering at Argonne National Laboratory’s Advanced Photon Source.

The discovery improves understanding of thermoelectric performance and may enable unconventional heat transport in future materials.

#Heat #Energy

More news

Material Science4 days ago · 2 min read

Researchers discover dual polarization behavior in a two-dimensional ferroelectric material

TlGaS2 single crystals show both in-plane and out-of-plane polarization, a rare combination in two-dimensional ferroelectrics that could widen options for ferroelectric transistors and non-volatile memory. Infrared spectroscopy revealed a soft phonon mode below 75 K, a signature tied to quantum ferroelectricity, along with weak structural changes across temperatures that lack clear heat-capacity signals, hinting at local rearrangements rather than conventional phase transitions.

Material Science4 days ago · 3 min read

Silicon nitride nanolayer reveals atomic structure and bonding

A β-Si3N4 nanolayer about 20 nm thick and continuous over several micrometers has been formed between carbon and silicon carbide without conventional oxide sintering additives, using a porous carbon framework infiltrated with molten silicon. Complementary atomic-resolution imaging resolved both silicon and nitrogen sublattices, confirming the ABAB stacking and corner-sharing tetrahedral network, while electron energy-loss spectroscopy and first-principles calculations linked the spectra to…

Material Science4 days ago · 4 min read

Angstrom-scale water channels help membranes recover lithium and purify salt

A polymer membrane with interconnected water-filled channels just 0.5 to 0.7 nanometers wide separates singly charged ions from multiply charged ones in both cationic and anionic systems. Built from Tröger's base-derived porous organic polymers, it cut the magnesium-to-lithium ratio in salt-lake brine roughly 500-fold across three electrodialysis stages, yielding 99.5 percent pure lithium carbonate, and enriched sodium chloride to 99.4 percent of ion mass from simulated seawater.